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CHAPTER 2 Light as Waves laser pointers, DVD players, etc) have much shorter cavities (a fraction of a millimeter) than gas lasers, so the harmonics of the fundamental cavity frequency are spaced farther apart than in a gas laser; however the emission spectrum of the semiconductor material is fairly broad so the cavity can still potentially support many modes As it happens these lasers often have coherence lengths at least as good as helium-neon lasers, though the mechanism by which they do that (effectively, the way in which one mode becomes dominant) is beyond the scope of this book The coherence length of a gas laser can be dramatically increased by the use of an etalon in the laser cavity This is typically a piece of very carefully polished glass with partially reflecting coatings on each surface.

5. Select the layer you want to alter from the Layer drop-down list. 6. Enter the text or code in the New HTML text area. You can enter either plain text, which is rendered in the default paragraph style, or any amount of HTML code, including <img>, <table>, or other tags.

∠ ∧ ∨ ∩ ∪ ∫ ∴ ∼ ≅ ≈ ≠ ≡ ≤ ≥ ⊂ ⊃ ⊄ ⊆ ⊇ ⊕ ⊗ ⊥ ⋅ ⌈ ⌉ ⌊ ⌋ 〈 〉

Because it is only 10 mm or so thick, its cavity frequency is quite high, and its harmonics are deliberately separated by more than the width of the laser medium s gain bandwidth If an etalon harmonic can be aligned with the central resonance of the cavity, only one output frequency will be allowed, and it can have roughly 50% of the power previously put out in the collection of frequencies This produces true single-frequency operation, and the coherence length can become many hundreds of meters However, the system is still vulnerable to mechanical vibrations, which alter the separation of the main cavity mirrors, and thermal drift (which does the same thing) Thus, although manufacturers cite some amazing coherence lengths, they have to be measured over the time of a holographic exposure to be useful predictors, and can be much shorter in practice.

The oxidation of l-alkenes usually gives 2-acetoxy-l-alkenes. 571 ,572 Oxidative acetoxylation of propylene with Pd(OAch may yield allylic or vinylic acetates depending on reaction conditions573 (see Section 9.2.6). The mechanism of vinyl acetate formation is closely related to that of the Wacker oxidation (Scheme 9.11); that is, acetoxypalladation-palladium hydride elimination takes place.498 ,503 The coordinated alkene is attacked by the external nucleophile acetate ion, or the attack may occur within the coordination sphere. ~-Hydride elimination followed by dissociation of the coordinated molecule yields directly the vinyl acetate end product. When reoxidation of Pd(O) with the Cu(II) + O2 system (used in the Wacker process) is applied, the process is less selective. Besides vinyl acetate, ethylene yields acetaldehyde, ethylidene diacetate, ethylene glycol mono- and diacetate, and chlorinecontaining compounds as wel1. 574 A complex reaction mixture consisting of isomeric vinylic acetates and allylic acetates, and 1,2-diol monoacetates is usually formed from terminal alkenes. 499 Because of the easy formation of palladium rc-allyl complexes through oxidation, higher alkene homologs tend to give allylic acetates as the main product. The oxidation of cyclohexene575 and internal alkenes 571 gives nearly exclusively allylic acetates, although the results are somewhat contradictory.499

7-12.1

These days, almost all medium- and large-frame lasers for holography include etalons (single-frequency operation makes life so much easier!), but we will still have to worry about it with heliumneon lasers..

TABLE 13.16 Trace for Composite Number 42,091

Right ascension Declination Magnitude CDS:POS_EQ_RA_MAIN CDS:POS_EQ_DEC_MAIN CDS:PHOT_MAG 189.594 84.342 204.637 23.654 8.938 45.837 12.3 11.7 13.1

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